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  • Are bio-based plasticizers for polylactic acid sustainable?
  • Research on bio-based plasticizers for polylactic acid (PLA), an environmentally friendly and biodegradable polyester, has advanced due to the increasing focus on sustainable materials.
  • What is a bio-based plasticizer for PLA?
  • Common bio-based plasticizers for PLA on the market today include acetyl tributyl citrate (ATBC), tributyl citrate (TBC), and polyethylene glycol (PEG). Among these, the Tg of PLA plasticized with 20 wt% TBC was found to decrease to 17.6 °C, while the elongation at break increased by a factor of 50.
  • Can bio-based plasticizers replace conventional plastic goods?
  • The challenge to implement this new class of natural-based plasticizers matches the increasing interest of material researchers and industries in new bio-based materials, made from renewable resources with the potential, not to totally replace but to reduce the use of conventional plastic goods.
  • What are natural based plasticizers?
  • Nowadays, there is increasing interest in the use of natural-based plasticizers that are characterized by low toxicity and low migration. This group includes epoxidized triglyceride vegetable oils from soybean oil, linseed oil, castor-oil, sunflower oil, and fatty acid esters (FAEs) .
  • What materials are used to make bio-based plasticizers for polylactic acid?
  • The raw materials for the synthesis of bio-based plasticizers for PLA primarily include vegetable oils, citric acid, oleic acid, sebacic acid, adipic acid, succinic acid, cardanol, isosorbide, and other small molecules (Fig. 3). Fig. 3. Origin and structural composition of bio-based plasticizer molecules designed for polylactic acid.
  • Which biobased precursors are used to make plasticizers?
  • A great variety of other biobased precursors have been used for the generation of plasticizers . Prominently among these have been cardanol [19 – 21] (a byproduct of cashew nut processing), tartaric acid [22 – 25] (a byproduct of winemaking) and derivatives of starch, isosorbide [26, 27] and the furanics [28 – 32].