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  • What is the difference between DOP and des?
  • Moreover, DOP and DES remain in the ester and DES phases, respectively, which benefits the product purification and DES recycle. As a result, DOP with high purity of 99.01 wt% can be acquired from the bottom of T1, after purifying the crude product in the ester phase of D3.
  • Can halogen-free deep eutectic solvent promote DOP synthesis in a biphasic system?
  • In this work, the process intensification of reactive extraction strategy is proposed to promote DOP synthesis in a biphasic system, with the halogen-free deep eutectic solvent (DES) [Im:2PTSA] as dual solvent-catalyst.
  • How does DOP synthesis work?
  • The schematic diagram of experimental setup for DOP synthesis. After the completion of reaction, the mixtures are settled for 6 h to obtain two phases, and product DOP enriches in the ester phase (upper phase) while DES and water stay in the DES phase (lower phase).
  • How does 2-eh affect DOP yield?
  • The excess of 2-EH can speed up the attainment of phase splitting, which is favorable for the forward reaction and hence increasing DOP yield. However, phase splitting will reduce the possibility of contact between reactants and DES, which delays the reaction to attain chemical equilibrium. 5.2. Kinetic modelling
  • What is the polarity of DOP?
  • As exhibited in Fig. 3, the σ -profile of DOP is mostly distributed within the range of −0.0084 e/Å 2 < σ < 0.0084 e/Å 2 and only a weak peak exists near the non-polar region, suggesting its very weak polarity.
  • What is a high DOP yield after a three-stage reaction?
  • At the condition of 130 °C (all reactors), 2-EH to PA mole ratio of 2.2 in PR, and DES mole fraction of 7.53 % (R1, R2 and R3), a high DOP yield of 98.61 % can be achieved after three-stage reactions. In Table 3, the composition of both phases in D1, D2 and D3 predicted by COSMO-RS were listed.