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- What are the future trends of rubber antioxidants?
- The perspectives on the future trends of rubber antioxidants have been presented. Elastomers, especially diene-rubbers containing unsaturated double carbon bonds in the main chains, are vulnerable to thermal/oxygen aging, which would make the elastomers less elastic and result in earlier failure of the elastomer products.
- How does rubber antioxidant work?
- To prolong the service life of rubber composites by retarding their aging processes, rubber antioxidant initially relies on the use of a coating, such as paraffin, and coal tar, to physically isolate oxygen, but this protective layer would quickly lose the utility due to wear.
- Are rubber antioxidants harmful?
- As shown in Table 1, many commonly used rubber antioxidants are damaging to human health and the environment. For example, the antioxidant MB (2-mercaptobenzimidazole), which is widely used in the manufacture of light-colored rubber products, is harmful to aquatic organisms and has a continuous effect.
- Can rubber antioxidants contain rare-earth ions?
- The recently reported rubber antioxidants containing rare-earth ions are summarized in Fig. 4, for instance, Sun et al. prepared a novel hindered phenol rare-earth complex (DTSm) (Fig. 4f) by a simple and green method using 3,5-di-tert-butyl-4-hydroxybenzoic acid (DT) and samarium chloride hexahydrate (SmCl3 ·6H 2 O) via coordination reaction.
- Are rubber antioxidants a rational design?
- The development of medical antioxidants also inspires the rational design of rubber antioxidants. Recently, Sun, et al. synthesized a novel antioxidant (APPT) containing aromatic amine, thiourea and allyl groups by the reaction between N-phenyl-p-phenylenediamine and allyl isothiocyanate (Fig. 3 b) .
- Why do we need antioxidants for rubber composites?
- Therefore, for a real application, the antioxidants are indispensable to retard the thermal-oxidative-aging process of the rubber composites and then prolong the service life. In this review, we systematically review the recent progress of antioxidants for rubber.
