What Plasticizers Do & How They Affect Properties | Osborne
Plasticizers act like a lubricant among polymer chains to reduce rigidity. Without them, synthetic polymer materials would be too brittle and rigid for any practical purpose. For example, plasticizers give rubber its extensibility. Approximately 90% of all plasticizers are used in polyvinyl chloride, or PVC.
Plasticizer
Plasticizers can be added to wallboard stucco mixtures to improve workability. In order to reduce the energy consumed drying wallboard, less water is added, which makes the gypsum mixture very unworkable and difficult to mix, necessitating the use of plasticizers, water reducers, or dispersants.
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Plasticizers may comprise 15–50% of a PVC formulation. By changing type and amount of plasticizer, properties can be tailored to requirements. Increasing plasticizer concentration increases flexibility, decreases tensile strength, and reduces hardness (e.g., Figure 1 ).
Superplasticizer
Superplasticizer. Superplasticizers ( SPs ), also known as high range water reducers, are additives used in making high strength concrete. Plasticizers are chemical compounds that enable the production of concrete with approximately 15% less water content. Superplasticizers allow reduction in water content by 30% or more.
- What are plasticizers & how do they work?
- Plasticizers are non-volatile organic substances (mainly liquids) added into a plastic or elastomer. They are also usually cheaper than other additives. They improve the following properties of the polymers: Plasticizers increase the flow and thermoplasticity of a polymer.
- Why are plasticizers important?
- Plasticizers prevent the development of microcracks in the polymer matrix. They thereby enhance material durability and resistance to mechanical stress. Well-chosen plasticizers can also improve resistance to UV exposure and chemical attack. This contributes to the long-term stability of the polymer.
- How to make a plastic product more flexible by adding plasticizers?
- The process of making the final plastic product more flexible by adding plasticizers is called plasticization. By adding the right type and amount of plasticizer, you can tweak the polymer properties to get exactly what you need.
- How does plasticizer affect the mobility of a polymer chain?
- The mobility of a polymer chain is more complex in the presence of plasticizer than what the Flory–Fox equation predicts for a simple polymer chain. The molecules of plasticizer take control over mobility of the chain - a polymer chain does not show an increase of the free volume around polymer ends.
- How do plasticizers affect a polymer?
- Well-chosen plasticizers can also improve resistance to UV exposure and chemical attack. This contributes to the long-term stability of the polymer. In specific applications, plasticizers can influence the dielectric properties of polymers.
- Why do plasticizers soften polymers?
- Internal plasticizers generally have bulky structures that provide polymers with more space to move around and prevent polymers from coming close together. Therefore, they soften polymers by lowering the Tg and, thus, reducing elastic modulus.