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  • What are Tackifiers & plasticizers in PSAs?
  • Source: Extance, A., “Using Tackifiers and Plasticizers in PSAs”, SpecialChem, February 9, 2009. Plasticizers are organic liquids or solids that are incorporated by melt processing or diffusion into a compatible polymer to reduce interaction between molecules and improve molecular mobility.
  • Does tackifier increase Tg?
  • Therefore, the tackifier addition raises the Tg of the final adhesive. Tackifiers operate opposite to plasticizers which lower the Tg of the adhesive formulation. The tackifying agent must be compatible with the base polymer. With hot-melt adhesives, consideration must also be given to the heat stability of the tackifier in the melt.
  • What are Tackifiers used for?
  • In adhesive and sealant formulations, tackifiers are used to generate tack and improve specific adhesion (peel strength). They are incorporated into base polymers which mainly lack tackiness and pressure-sensitive properties but provide cohesion.
  • Does a tackifier reduce the modulus of a polymer?
  • Because tackifiers have lower molecular weight than the base polymer, they dilute the polymeric network and reduce the modulus. A plasticizer by itself could also reduce the modulus, but this is generally an ineffective approach because the Tg of the entire formulation is significantly reduced.
  • How do I choose a tackifier for a hot-melt adhesive?
  • With hot-melt adhesives, consideration must also be given to the heat stability of the tackifier in the melt. Tackifiers with unsaturation could potentially gel while the adhesive is in the melt phase. They should also have a relatively low surface tension so as to readily wet the substrate.
  • Can a tackifier be used in a polystyrene block copolymer?
  • The tackifier can be directed to either or both phases depending on its compatibility. For example, in styrene block copolymers the formulator may want the polystyrene phase to remain glassy for optimum cohesive properties. The aliphatic C5 resins, which are more compatible in the non-styrene phase, therefore are more likely to be used.