Selecting Tackifiers for Adhesives and Sealants

                                               
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  • Does tackifier increase Tg?
  • Therefore, the tackifier addition raises the Tg of the final adhesive. Tackifiers operate opposite to plasticizers which lower the Tg of the adhesive formulation. The tackifying agent must be compatible with the base polymer. With hot-melt adhesives, consideration must also be given to the heat stability of the tackifier in the melt.
  • What are Tackifiers used for?
  • In adhesive and sealant formulations, tackifiers are used to generate tack and improve specific adhesion (peel strength). They are incorporated into base polymers which mainly lack tackiness and pressure-sensitive properties but provide cohesion.
  • Does a tackifier reduce the modulus of a polymer?
  • Because tackifiers have lower molecular weight than the base polymer, they dilute the polymeric network and reduce the modulus. A plasticizer by itself could also reduce the modulus, but this is generally an ineffective approach because the Tg of the entire formulation is significantly reduced.
  • How do I choose a tackifier for a hot-melt adhesive?
  • With hot-melt adhesives, consideration must also be given to the heat stability of the tackifier in the melt. Tackifiers with unsaturation could potentially gel while the adhesive is in the melt phase. They should also have a relatively low surface tension so as to readily wet the substrate.
  • What is a hydrocarbon resin tackifier?
  • Hydrocarbon resins tackifiers are either aliphatic, aromatic, or mixtures of the two. Hydrocarbon resin tackifiers are polymerized to raise their softening points to a level that is useful in adhesives. They are low molecular weight amorphous synthetic polymers. Table below summarizes the most common types of hydrocarbon resin tackifiers.
  • Why do formulators use Tackifiers?
  • In practice, formulators use tackifiers to make the correct balance between adhesion and cohesion which is dependent on the end-use application. They do this by lowering the modulus and increasing the glass transition temperature of the final adhesive. Tackifiers must be considered with regard to: