Synthesis method of polyether ester plasticizer - Google
(1) preparation of the prepolymer of carboxy blocking: add 1.2mol (175.39g) hexanodioic acid and 1mol (106.11g) glycol ether in four-hole boiling flask, under the environment of nitrogen, 180 DEG...
Synthesis of novel plasticizer ester end-capped oligomeric lactic acid
In this work, a novel high efficiency plasticizer, an ester-capped oligomeric lactic acid mixture (EOL), was successfully synthesized by a two-step esterification reaction, with L -lactic acid as the main raw material. The structure of EOL was characterized by using FT-IR, 1 H NMR and time of flight mass spectrometry (TOF-MS).
Polyglycerol fatty acid ester plasticizer and preparation method thereof
The Polyglycerine measuring and hydrogenated vegetable oil (or lipid acid) are added in reactor; under basic catalyst, be heated to 170-230 DEG C; under vacuum or under protection of inert gas,...
Ester plasticizers for polyvinyl chloride | SpringerLink
The review covers information from patents and papers that have been published in the past 5 years and deal with the synthesis of ester plasticizers for polyvinyl chloride. The main trends in the progress of this field are analyzed. Data on new esterification catalysts are presented. Particular attention is paid to plasticizers derived from terephthalic acid, which show promise for replacing
Preparation of Esters - Chemistry LibreTexts
To make a small ester like ethyl ethanoate, you can gently heat a mixture of ethanoic acid and ethanol in the presence of concentrated sulphuric acid, and distil off the ester as soon as it is formed. This prevents the reverse reaction happening. It works well because the ester has the lowest boiling point of anything present.
- What is an ester plasticizer?
- An ester plasticizer, in its simplest concept, is a high-boiling organic solvent that when added to an elastomeric polymer reduces stiffness and permits easier processing.1 For general performance applications, compounders require moderate performance in several areas without particular emphasis on any one.
- What factors affect Plasticizer-elastomer interaction?
- Plasticizer–elastomer interaction is governed by many factors, such as solubility parameter, molecular weight and chemical structure. Ester plasticizers are selected based upon cost/performance evaluation. The rubber compounder must evaluate ester plasticizers for compatibility, processability, permanence and performance properties.
- What is a general performance ester plasticizer?
- Some general performance ester plasticizers used in the marketplace today are DOA, DIDA, DIDP, DOP, DINP and other phthalates and adipates made from straight-chain alcohols of 7–11 carbons in length. Ester plasticizers are commonly used only for their as-molded, low-temperature contribution.
- How to choose a high-performance ester plasticizer?
- The rubber compounder must evaluate ester plasticizers for compatibility, processability, permanence and performance properties. The study of these properties by the rubber compounder will contribute to the selection of a high-performance ester plasticizer. 1.
- Are plasticizers suitable for elastomers and high-temperature polymers?
- Plasticizers commonly used for the traditional and the high-temperature polymers are extractable, incompatible or too volatile. This paper provides information on plasticizers that are designed for traditional elastomers and high-performance polymers.
- Can polymeric esters enhance a high-performance elastomer?
- One example of how polymeric esters can enhance a high-performance elastomer is depicted in Figure 3. High-saturated nitrile is used in many high-heat applications. The use of 8-10 trimellitate is well documented as the plasticizer of choice for HNBR.
