Competitive adsorption of diethyl phthalate (DEP), dibutyl

                                               
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Adsorption and removal of phthalic acid and diethyl phthalate

                                               
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Competitive adsorption of diethyl phthalate (DEP), dibutyl

                                               
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Adsorption of diethyl phthalate ester to clay minerals

                                               
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Genotoxic activity of endocrine disrupting compounds commonly

                                               
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  • Does dibutyl phthalate (DBP) adsorption work on corncob biochar (fresh and oxidized?
  • So far, the competitive adsorption of PAEs to biochar has not been reported. In this study, the competitive adsorption of Dibutyl phthalate (DBP) and Di (2-ethylhexyl) phthalate (DEHP) on corncob biochar (fresh and oxidized) was investigated, and experiments of kinetics, isotherms, and thermodynamics were conducted.
  • What are the adsorption kinetics of DBP and DEHP?
  • Adsorption kinetics of DBP and DEHP under mono (a, c) and binary (b, d) conditions. To further understand DBP and DEHP’s adsorption actions, the adsorption kinetics were analyzed using the pseudo-first-order model and the pseudo-second-order model. All models and the parameters were presented in Supplementary Material S3.
  • Does DEHP inhibit DBP adsorption?
  • Apparently, in a binary PAEs system with high PAEs concentration, the accessible adsorption sites on biochar were preferentially occupied by DEHP, contributing to DBP adsorption inhibition. In contrast, the adsorption of DEHP was only marginally inhibited.
  • Which phthalate has a bioaccumulation potential?
  • For example, some of the PAEs, e.g., Dibutyl phthalate (DBP); Di (2-Ethylhexyl) phthalate (DEHP); Butyl Benzyl phthalate (BBP) and Diethyl phthalate (DEP), have bioaccumulation potentials and are considered endocrine-disrupting chemicals and classified by many countries as "priority pollutants" (Lu et al., 2009).
  • Are DBP & DEHP adsorbable in environmental samples?
  • DBP and DEHP are the most frequently reported PAEs in environmental samples (Peijnenburg and Struijs, 2006). Because of their prevalence in the environment, it is meaningful to compare DBP and DEHP’s adsorption behavior.
  • Why is DBP more adsorbable than DEHP?
  • The higher hydrophobicity of DEHP could explain the stronger adsorption of DEHP than DBP. In contrast, DBP’s faster adsorption could be attributed to its smaller size and shorter chains, therefore faster diffusion.