5 Technical and economical assessment of alternative
DEHP has substitution factor 1 per definition, while plasticisers needing lower concentration (more effective) have lower values, and plasticisers needing higher concentrations have higher effectiveness value. *2: According to Lanxess, 2009, 2009b. NA = not available Table 5.3 below shows some performance data for ASE compared to DEHP.
Phthalates found in diverse array of foods, from coffee to
“The risk of exceeding the tolerable daily intake (TDI) was high for DEHP and DBP in fish, fat and oils, cereals, and milk and dairy products for children and adults. Fat and oils are the most critical food for DEHP, DBP, BBP, and DINP.” The highest concentration of an individual PAE in one product was DEP in a lettuce bag (16.5 mg/kg).
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- What is a substitute for DBP?
- Has very similar application properties to DBP and may therefore be used to substitute for DBP in most, if not all, of its applications. The main alternatives to DEHP have been the two phthalates di-isononyl phthalate (DINP) and di-isodecyl phthalate (DIDP).
- Is di-isobutyl phthalate a substitute for DBP?
- P for many applications has been replaced by other sub-stances. The main marketed all-round alternative to DBP is Di-isobutyl phthalate (DIBP). Di-isobutyl phthalate (DIBP) has applic on properties very similar to the properties of DBP and may therefore be used to substitute for DBP in most, if not all, of its applications
- What is the prevalence of DBP in food samples?
- DBP was detected in 23 out of 37 samples (62%), BBP in 11 out of 37 samples (30%), DEHP in 24 out of 37 (65%) food items, followed by DINP which was detected in 31 out of 37 (84%) of the food items. DIDP was detected in 14 out of 37 samples (38%).
- Is DINCH a suitable alternative to DEHP & BBP?
- It was found in 25% and 48%, respectively, of the analysed products. It was also reported as used for toys by Danish toy manufacturers (with contract production in China). The data available does not allow a closer assessment of DINCH's technical suitability as alternative to DEHP, DBP and BBP.
- What percentage of wine samples have DBP & DBP above LOQ?
- For spirits, 90% of samples had DBP and DEHP and 40% had BBP above the LOQ (10 μg/L). DINP and DIDP were neither detected in wines nor in spirits (LOD = 20 μg/L).
- Is DINP a transient phthalate?
- Similarly, the CEP Panel considered that in animal studies some effects of DINP, e.g. the reduction of fetal testosterone production and AGD, are transient and less pronounced compared to other phthalates, which instead have been classified as Repr. 1B (among others DBP, BBP, DEHP).
