ETHER-BASED REACTIVE PLASTICIZER FOR PLASTIC BONDED EXPLOSIVES

                                               
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Reactive Energetic Plasticizers Utilizing Cu-Free Azide

                                               
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US20140031593A1 - Ether-based reactive plasticizer

                                               
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Bum Jae Lee's scientific contributions - ResearchGate

                                               
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Central European Journal of Energetic Materials - ResearchGate

                                               
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  • Which polymer is used to encapsulate explosives?
  • Nowadays, the current practice is to encapsulate the explosive in a binder, composed of a polymer such as hydroxy- terminated polybutadiene (HTPB) crosslinked with isocyanates, and containing a plasticiser such as dioctyl adipate (DOA). Other polymers include carboxy-terminated polybutadiene (CTPB) and hydroxy-terminated polyethers (HTPE) .
  • Can energetic binders be used in cast-cured polymer bonded explosives?
  • In an effort to comply with Insensitive Munitions (IM) criteria, energetic binders comprising polymer and plasticiser(s) are finding use in cast-cured polymer bonded explosives and cast composite rocket propellants.
  • What are energetic plasticisers?
  • Energetic Plasticisers The primary role of energetic plasticisers in energetic material formulations is to modify the mechanical properties of the charge to improve safety characteristics. This is achieved by softening the polymer matrix and making it more flexible.
  • Which polymers are energetic binders?
  • Miscellaneous nitrogen-containing polymers that have found use as energetic binders include polyvinylnitrate, polynitrophenylene, nitramine polyethers and N,N'-bonded epoxy binders. Recently the inert poly(furfuryl glycidyl ether) has also been identified as a possible route to energetic binders .
  • What is cast cured polymer bonded explosives (PBX)?
  • One approach to less sensitive explosives is the development of cast-cured polymer bonded explosives (PBX), in which the explosive ingredient is suspended in a polymeric binder, cured in-situ as a tough elastomeric rubber which absorbs and dissipates the energy from hazardous stimuli.
  • What is a non-energetic plasticiser?
  • Non-energetic plasticisers are effective in improving mechanical properties, but degrade the output of the formulation by reduction of the overall oxygen balance. Examples of non-energetic plasticisers include the esters - acetyl triethyl citrate, diethyl adipate, diethyl sebacate and dioctyl adipate.