Miscibility and dynamical properties of cellulose acetate/plasticizer

                                               
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Technical information for Cellulose Acetate

                                               
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Thermal Properties of Plasticized Cellulose Acetate and Its β

                                               
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Study on Cellulose Acetate Butyrate/Plasticizer Systems by

                                               
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  • Can cellulose acetate be used as a plasticizer?
  • Due to their high glass transition temperature, cellulose acetate-based systems are processed when blended with plasticizers. It is thus of utmost importance to study the miscibility and plasticizing effects of various molecules. We prepared CDA films via solvent casting method with diethyl phthalate as the plasticizer.
  • Is secondary cellulose acetate plasticized by diethyl phthalate miscible?
  • We study the miscibility and dynamical properties of secondary cellulose acetate plasticized by diethyl phthalate (DEP). Partial miscibility (characterized by differential scanning calorimetry) is observed above 25 wt% of DEP content. The α-relaxation of the system and its VFT/WLF behavior are studied over a broad frequency range.
  • Are plasticized cellulose acetate systems dielectric?
  • Most of these dielectric studies, however, have been focused on cellulose and its derivatives, and only few results have been reported about dielectric properties of plasticized cellulose acetate systems. Seymour et al., 1979 focused on phthalate plasticizers such as dioctyl phthalate and diphenyl phthalate.
  • What causes -relaxation of plasticized cellulose acetate polymers?
  • (Bao, 2015) have assumed that the β-relaxation of plasticized cellulose acetate polymers results from two different contributions: βrelaxation of cellulose acetate rich phase (which correspond to the secondary relaxation of unplasticized CDA) and α'-relaxation of plasticizer rich phase of plasticized CDA (specific to the CDA/plasticizer systems).
  • What is partial miscibility of cellulose acetate system?
  • Partial miscibility (characterized by differential scanning calorimetry) is observed above 25 wt% of DEP content. The α-relaxation of the system and its VFT/WLF behavior are studied over a broad frequency range. A new secondary relaxation is found for DEP-plasticized cellulose acetate system.
  • What is the dynamical behavior of cellulose acetate (CDA)?
  • The dynamical behavior of CDA is supposed to be governed by H-bonding and dipolar interaction network. Due to their high glass transition temperature, cellulose acetate-based systems are processed when blended with plasticizers. It is thus of utmost importance to study the miscibility and plasticizing effects of various molecules.