Development of lignin-based polycarboxylates as a plasticizer

                                               
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  • What is a polycarboxylate superplasticizer?
  • Polycarboxylate superplasticizers (PCEs) are comb-shaped polymers with an anionic backbone and several nonionic pendant chains, which typically are comprised of polyethylene glycols. In this study,...
  • Is PCE 45pc2 a jellyfish-like superplasticizer?
  • Surprisingly, the hydrodynamic radius of the comb-shaped PCE 45PC2 was similar to that of the jellyfish-like superplasticizer, in spite of its considerably higher molecular weight.
  • Does a superplasticizer contain a hyperbranched polyglycerol scaffold?
  • Therefore, this study aims to present the synthesis of a new type of superplasticizer, which contains a hyperbranched polyglycerol scaffold, and to evaluate the dispersing properties of such moieties in cement.
  • What is a carboxymethylated hyperbranched polyglycerol?
  • Moreover, a carboxymethylated hyperbranched polyglycerol was synthesized that does not comprise a linear EO/PO side chain. This polymer was denoted as TMP (hyp.PG) (COOH) n and prepared in a two-step synthesis from trimethylol propane (TMP) and glycidol (see Scheme 2).
  • Which polymer has a higher molar mass than a jellyfish-like superplasticizer?
  • Considering the molar masses of the polymers, it became apparent that TMP (hyp.PG) (COOH) n holds a higher proportion of the carboxymethylated hyperbranched polyglycerol skeleton than the jellyfish-like superplasticizer. The hydrodynamic radii of the synthesized polymers are presented in Table 2.
  • What is the structure of a jellyfish-like superplasticizer?
  • Structural Analysis of the Polymers The hyperbranched structure of the jellyfish-like superplasticizer was achieved by anionic ring opening polymerization of glycidol using a partially deprotonated bis-glycidolized Jeffamine as initiator.