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ANALYSIS OF ALTERNATIVES and SOCIO-ECONOMIC ANALYSIS Public

                                               
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  • Can green chemistry prevent regrettable substitutions?
  • Preventing regrettable substitutions is a considerable challenge for scientists globally. Green chemistry, (69,70) and intelligent toxicology (71,72) can provide a safe way forward as elaborated in a proposed general framework to avoid regrettable substitutions in Figure 2.
  • What is regrettable substitution?
  • Regrettable substitution has an extensive historical narrative and is still a common occurrence (Table 1), resulting in negative repercussions on public health and environment.
  • Does DM-DBP reduce VOC?
  • Unfortunately, for DM-DBP (10 mg/ml) modified devices, dramatically reduced VOC of 0.879 V, JSC of 13.71 mA cm −2 and FF of 62.1 % are observed, leading to a poor PCE of 7.48 %.
  • What is the difference between DBP and DM-DBP?
  • Compared to DBP and M-DBP, DM-DBP shows denser negative charge distribution around O atom of both methoxy groups and bromine units, and its positive charges mainly concentrate in the two methyl units.
  • What is the thermal decomposition temperature of DBP and DM-DBP?
  • As displayed in Figure S1a of thermogravimetric analysis (TGA), the thermal decomposition temperatures of DBP, M-DBP and DM-DBP at 5 % weight loss gradually increase as 118, 122, and 171 °C.
  • What is an example of informed substitution?
  • For instance, the replacement of chromated copper arsenate (CCA - carcinogenic) with alkaline copper quaternary (ACQ) as a wood preservative product is considered as successful example of informed substitution.