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Hydrogenation of dioctyl phthalate over a Rh-supported Al modified

                                               
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Plasticizers - Chemical Economics Handbook (CEH) | S&P Global - IHS Markit

                                               
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  • What is dioctyl phthalate (DOP)?
  • 1. Introduction Dioctyl phthalate (DOP) is one of the most widely used plasticizers with low volatility and high plasticizing efficiency. Although new product like dioctyl terephthalate is more recommended, DOP accounts for more than half of the market share for plasticizers.
  • What is phthalic anhydride (PA) and 2-ethylhexanol (eh)?
  • It has been generally utilized for the flexible polyvinyl chloride (PVC) plastic production owing to its low cost. DOP is traditionally synthesized by the catalytic esterification between phthalic anhydride (PA) and 2-ethylhexanol (2-EH) . The synthetic process includes two-step reactions of esterification: (1) (2)
  • Where can I buy phthalic anhydride and p-toluenesulfonic acid?
  • Materials Dioctyl phthalate, phthalic anhydride, 2-ethylhexanol, n-tridecane, choline chloride, imidazole, and p -toluenesulfonic acid are purchased from Adamas-beta (Shanghai, China) with purity above 99%.
  • Can halogen-free deep eutectic solvent promote DOP synthesis in a biphasic system?
  • In this work, the process intensification of reactive extraction strategy is proposed to promote DOP synthesis in a biphasic system, with the halogen-free deep eutectic solvent (DES) [Im:2PTSA] as dual solvent-catalyst.
  • What is the polarity of DOP?
  • As exhibited in Fig. 3, the σ -profile of DOP is mostly distributed within the range of −0.0084 e/Å 2 < σ < 0.0084 e/Å 2 and only a weak peak exists near the non-polar region, suggesting its very weak polarity.