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Eects of molecular design parameters on plasticizer

                                               
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  • Which plasticizer has the best plasticizing effect on PVC and PLA films?
  • According to the above Tg results of plasticized PVC and PLA films, the AcMAE-C6 plasticizer exhibited the best plasticizing effect on PLA films as well as PVC films, and this phenomenon seems to be due to the structure of AcMAE-C6 having the best compatibility with both PVC and PLA.
  • How much weight does a PVC film lose with a plasticizer?
  • The weight loss percentages of the PVC films with DEHP and DOA commercial plasticizer were 0.07 wt.% and 0.57 wt.%, respectively. In general, leaching property depends on the molecular weight of a plasticizer, compatibility and interaction strength between a plasticizer and a polymer matrix.
  • Which plasticizer has the lowest TG value?
  • The lowest Tg value (28.8 °C) was observed in the PLA film containing the AcMAE-C6 plasticizer, and the Tg value of the PLA film with AcMAE-C4 was 38.0 °C, lower than those of the PLA films containing DOA (53.1 °C) and DEHP (53.6 °C).
  • What plasticizers are used for PVC?
  • Some of the most common plasticizers that are currently being utilized for PVC are aromatics and aliphatic esters, typically di (2-ethylhexyl) phthalate (DEHP) and dioctyl adipate (DOA). There have been concerns over the use of DEHP, as it negatively impacts human health and the environment .
  • Which plasticizer has the lowest storage modulus?
  • The lowest storage modulus value (0.03 GPa) was observed for PLA/AcMAE-C6, and the storage modulus (0.69 GPa) of PLA/AcMAE-C4 was also lower than those of PLA/DOA (1.29 GPa) and PLA/DEHP (1.59 GPa) film. PLA films containing the other plasticizers showed similar storage moduli to those containing the commercial plasticizer DOA and DEHP. Fig. 4.
  • Which plasticizer is best for PVC film elongation?
  • By comparing the percent elongation of PVC films containing different plasticizer types, AcMAE-C6 is found to be the most effective plasticizer (780%), followed by AcMAE-C8 (757%), AcMAE-iC8 (729%), AcMAE-iC13 (595%), and AcMAE-C4 (477%).