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Metalorganic frameworks as recyclable catalysts

                                               
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Oxoviflex (DOTP, DEHT) - Oxoplast

                                               
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DOA Renew 20 Plasticizer | Eastman

                                               
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Bis(2-ethylhexyl) terephthalate

                                               
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  • What is the difference between DOP and DOTP plasticizer?
  • In summary, interest in alternative plasticizers has been increasing, as phthalates are among the harmful chemicals and forbidden in some countries. DOTP plasticizer has been commercialized around 1975 . Due to the structural difference, DOTP is less toxic than DOP. DOTP has been used alternative to phthalate.
  • Is DOTP a good alternative to phthalate?
  • DOTP has been used alternative to phthalate. Since DOTP is a petroleum-based plasticizer, some researchers are concerned about using it. However, it is a significant advantage that DOTP can be produced from waste PET in addition to direct esterification. Besides, the production cost is generally lower compared to bio-based plasticizers.
  • Why is DOTP more stable than other plasticizers?
  • Also, the stability of DOTP is greater than that of the other plasticizers due to the compensation ratio. Wang et al. investigated thermal degradation kinetics of PVC with different plasticizers; DOTP, DOP, ATBC, acetyl trioctyl citrate (ATOC), TOTM, and isosorbide ester (ID-37).
  • Is DOTP Plasticized PVC a good plasticizer?
  • According to the results, DOTP has high compatibility with PVC, and DOTP plasticized PVC shows good migration, mechanical and thermal properties. DOTP is a promising plasticizer due to having good properties, low production cost, and low toxicity. PVC, yaygın olarak tercih edilen termoplastiklerden biridir.
  • Can Dioctyl terephthalate be used as a plasticizer for PVC?
  • Direct esterification of the obtained TPA and 2-ethyl-1-hexanol at 160 o C for 6 hours yielded dioctyl terephthalate or DOTP. The resulting DOTP was clear and slightly yellowish with a specific gravity of 0.936, a refractive index of 1.472 and an acid value of 0.0044 mg KOH/g. The possibility of using DOTP as a plasticizer for PVC was studied.
  • What are the optimal reaction conditions to obtain DOTP?
  • Optimum reaction conditions to obtain DOTP were evaluated as 1:3.8 for molar ratio of PET/2-EH and 13.10% for the quality ratio of catalyst/PET. Besides, when reaction temperature and time were 210 °C - 220 °C and 3 h, the productivity value of DOTP enhanced by 96.18% .