Selecting Plasticizers for Adhesives and Sealants

                                               
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Eastman Plasticizers for Adhesives

                                               
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Phthalates - Adhesives Ingredients Selection

                                               
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Improved Plasticizers Help to Fill the Gap in Polysulfide Sealants

                                               
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Selecting Tackifiers for Adhesives and Sealants

                                               
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  • What is a plasticizer used for?
  • Plasticizers have been used to give polymers a permanent adhesive character (pressure sensitivity), or to regulate their adhesion-cohesion balance to achieve removability. For example, plasticizers can be incorporated into peelable pressure-sensitive adhesive to soften the adhesive, and thus improve peelability and clean removal.
  • What types of plasticizers are used in adhesives & sealants?
  • Oils (like paraffinic, naphthenic, and aromatic) are used mainly as plasticizers in non-polar adhesives. These are generally used in the hot-melt adhesives and sealants. Base polymers include the mid-blocks of styrene-butadiene copolymers and polyolefin-based adhesives. Polymeric plasticizers are used frequently in adhesives and sealants.
  • How do I choose a plasticizer?
  • The key evaluation parameters in choosing a plasticizer are: Plasticizers will reduce the melt viscosity of hot-melt adhesives and 100% solids adhesives & sealants. However, the addition of certain plasticizers to a polymeric emulsion will usually result in increased viscosity.
  • Do plasticizers reduce the viscosity of adhesives & sealants?
  • Plasticizers will reduce the melt viscosity of hot-melt adhesives and 100% solids adhesives & sealants. However, the addition of certain plasticizers to a polymeric emulsion will usually result in increased viscosity. This effect can be used to formulate a waterborne adhesive having greater coating thickness build-up.
  • What is plasticizer compatibility?
  • Plasticizer compatibility is the key to plasticizer performance in adhesives and sealants. In latex systems, compatibility can be assessed by observing the viscosity increase after the addition of the plasticizer and by observing the clarity of a cast film of the plasticized adhesives.
  • Why are plasticizers used as extenders?
  • Plasticizers may also be one of the least expensive additives used in adhesives and sealants, and they can be used in relatively large concentrations depending on the application and formulation (up to 100 parts by weight per 100 parts of the base polymer). For these reasons, they are sometimes used as extenders for cost-reducing purposes.