Methods for determination of plasticizer migration
2 Test methods for plasticizer migration In general, plasticizer migration from PVC synthetic materials can proceed via three different mechanisms, namely volatilization, exudation or extraction, depending on the environment where the PVC coatings are located.
Plasticiser loss from plastic or rubber products through
Two kinetics-dominating migration modes The migration of plasticiser from polymers to a gas phase is a two-step process that includes diffusion from the polymer bulk to the surface followed by...
A Strategy for Nonmigrating Highly Plasticized PVC - Nature
Flexible samples with 0.32:1 plasticizer over PVC were selected to ensure a high migration rate of plasticizers. These results indicated that the new DOP-like plasticizer in PVC was...
Plasticizer Migration: What is it and why is it a problem
Collectively these are known as plasticizer migration. Plasticizers are often put into materials to make them more flexible or malleable. As an example, PVC is heavily-plasticized to increase its flexibility. So when bonding PVC with adhesives, those plasticizers can migrate from the PVC into the adhesive.
Prevent Plasticizer Migration with Vinyl Bonding Solutions
Plasticizer migration occurs when plasticizers migrate from one material to another, typically from the vinyl to the adhesive which adheres it to the substrate itself. Plasticizer migration occurs over time and can be accelerated with heat.
- Can plasticizers migrate from flexible PVC parts to other media?
- An accelerated method has been set up in order to study the capacity of migration of different commercial plasticizers from flexible PVC parts towards other media kept in contact with it; in this case, polystyrene (PS) has been used as example.
- Do Plasticizers improve the migration resistance of plasticized PVC material?
- This indicates that a moderate increase in the relative molecular weight of the plasticizer can effectively improve the migration resistance of the plasticized PVC material, a finding consistent with the results from the resistance tests. There has been no clear evidence observed regarding the plasticization process of plasticizers in PVC.
- How can we measure plasticizer migration in coextruded PVC pipes?
- Technologically relevant for plasticizer migration studies in coextruded PVC pipes. This study introduces and validates an effective approach for monitoring the plasticizer amount and its concentration profile in polyvinyl chloride (PVC) formulations. The method combines gravimetric measurements with confocal Raman depth profiling analysis.
- Can macromolecular engineering improve the migration resistance of polymeric plasticizers?
- This paper summarizes current literature on the migration of monomeric and polymeric PVC plasticizers from medical materials, food packaging, and toys. Especially highlighted is macromolecular engineering as a tool to increase the plasticizing efficiency and migration resistance for polymeric plasticizers.
- Do plasticizers migrate from PVC to distilled water?
- Nevertheless, plasticizer migration from PVC blends with only one plasticizer, including extraction in distilled water, exudation and volatility, was investigated, showing the highest volatility of PVC/CA (about three times higher than for PVC/DOTP) and comparable extraction in distilled water.
- Why is migration resistance important for PVC products?
- The migration resistance of plasticizers is a pivotal performance criterion for PVC products in the food packaging industry, as it directly impacts food safety.