Plasticizer - an overview | ScienceDirect Topics
Plasticizers are low molecular weight substances added to a polymer solution to promote its plasticity and flexibility. Therefore, the plasticizers make the polymer solution more suitable for the application of film coating. There should be chemical similarities between the polymers and its plasticizers.
Plasticizers – Benefits, Trends, Health, and Environmental
Plasticizers soften the PVC to make it flexible and bendable. This opens up a huge range of possibilities for new applications. One of the main benefits of plasticizers is the durability they confer onto PVC applications, which can ensure high performances for up to 50 years.
IOPscience
IOPscience
What Plasticizers Do & How They Affect Properties | Osborne
Plasticizers act like a lubricant among polymer chains to reduce rigidity. Without them, synthetic polymer materials would be too brittle and rigid for any practical purpose. For example, plasticizers give rubber its extensibility. Approximately 90% of all plasticizers are used in polyvinyl chloride, or PVC.
Plastic Additives: Polymer Stabilizers, Plasticizers and
Plasticizers can increase the flexibility, extensibility, and plasticity of plastics because of their ability to weaken the van der Waals forces between polymer molecules, thereby increasing the mobility of polymer molecular chains and reducing the crystallinity of polymer molecular chains.
- What happens when plasticizers are added to polymers?
- When plasticizers added to polymers do not lead to chemical bonding, the process is referred to as external plasticization. Polymer molecules used to achieve internal plasticization are either copolymerized into the polymer structure or reacted with the original polymer.
- How does plasticizer affect the mobility of a polymer chain?
- The mobility of a polymer chain is more complex in the presence of plasticizer than what the Flory–Fox equation predicts for a simple polymer chain. The molecules of plasticizer take control over mobility of the chain - a polymer chain does not show an increase of the free volume around polymer ends.
- How is plasticization achieved in polymer morphology?
- Plasticization is achieved by incorporating a plasticizer into polymer matrix, copolymerization, or blending. Among those, adding plasticizer is the most common and simplest way to modify polymer morphology. Plasticizer can lessen the intermolecular forces along the polymer chains. As a result, free volume was increased and T g was lowered.
- Why do polymers need plasticizers?
- The plasticizers reduce the glass transition temperature, and the viscosity of the polymer also enhances the flexibility and processability of polymer materials. The main problem of these additives is that, over time, they migrate from the polymeric matrix and exude to the surface of polymeric matrix.
- How do plasticizers affect the microstructure of amorphous and semicrystalline polymers?
- Plasticizers affect the microstructure of amorphous and semicrystalline polymers to achieve the desired properties. All polymer materials have amorphous regions that are disorganized and inefficiently packed, allowing some degree of flexibility.
- Can plasticizers reduce material degradation over time?
- The design of new plasticizers compatible with the polymer at high concentrations, tailored to be effective in lowering the glass transition temperature, and with a low tendency to migration could considerably reduce material degradation over time.
