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Research progress of novel bio-based plasticizers and their

                                               
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  • What are natural based plasticizers?
  • Nowadays, there is increasing interest in the use of natural-based plasticizers that are characterized by low toxicity and low migration. This group includes epoxidized triglyceride vegetable oils from soybean oil, linseed oil, castor-oil, sunflower oil, and fatty acid esters (FAEs) .
  • Are bio-based plasticizers sustainable?
  • Bio-based plasticizers, derived from renewable biomass sources like vegetable oils, cardanol, citric acid, starch, cellulose, and lactic acid, represent an environmentally sustainable class of plasticizers.
  • What are biodegradable plasticizers?
  • Biodegradable plasticizers such as soybean oil (SO), epoxidized soybean oil (ESO), dibutyl phthalate (DBP) and triethyl citrate (TEC) were added to poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) films, enhancing their thermal and mechanical properties. TEC or DBP presented better plasticizing effects than SO and ESO for PHBV .
  • What is a bio-based plasticizer for PLA?
  • Common bio-based plasticizers for PLA on the market today include acetyl tributyl citrate (ATBC), tributyl citrate (TBC), and polyethylene glycol (PEG). Among these, the Tg of PLA plasticized with 20 wt% TBC was found to decrease to 17.6 °C, while the elongation at break increased by a factor of 50.
  • What is a plasticizer?
  • In general, plasticizers can be defined as low molecular weight (between 300 and 600) , high boiling point materials which are added to a film-forming polymer to enhance its flexibility, durability, processability, and workability . Their addition can avoid shrinking during storage , and in some cases reduce costs .
  • What materials are used to make bio-based plasticizers for polylactic acid?
  • The raw materials for the synthesis of bio-based plasticizers for PLA primarily include vegetable oils, citric acid, oleic acid, sebacic acid, adipic acid, succinic acid, cardanol, isosorbide, and other small molecules (Fig. 3). Fig. 3. Origin and structural composition of bio-based plasticizer molecules designed for polylactic acid.