Plasticizer - an overview | ScienceDirect Topics

                                               
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Plasticizers – Benefits, Trends, Health, and Environmental

                                               
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Plasticizer

                                               
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Plastic Additives: Polymer Stabilizers, Plasticizers and

                                               
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The advantages and disadvantages of plasticizers - ZhangJia

                                               
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  • How is plasticization achieved in polymer morphology?
  • Plasticization is achieved by incorporating a plasticizer into polymer matrix, copolymerization, or blending. Among those, adding plasticizer is the most common and simplest way to modify polymer morphology. Plasticizer can lessen the intermolecular forces along the polymer chains. As a result, free volume was increased and T g was lowered.
  • Why do plasticizers reduce TG?
  • The reduction of Tg is proportional to the temperature difference between the Tg of the polymer and plasticizer. Plasticization improves the flexibility and processability of polymers. Certain factors can counteract or restrict this enhancement. Certain polymers may have limited compatibility with specific plasticizers, hindering their integration.
  • Are plasticizers bad for the environment?
  • Plasticizers can weaken intermolecular forces along the polymer chains, thus increasing free volume and lowering the glass transition temperature. For this reason, polymers with plasticizers have improved ductility. Nowadays, there is a growing concern among consumers regarding the detrimental effects of synthetic plastics on the environment.
  • How do you plasticize a polymer?
  • A polymer can be internally plasticized by chemically modifying the polymer or monomer. This increases flexibility. It involves copolymerization of the monomers of the desired polymer (having high Tg) and that of the plasticizer (having low Tg) so that the plasticizer is an integral part of the polymer chain.
  • How do plasticizers affect polymer morphology?
  • Among those, adding plasticizer is the simplest and most commonly used way to modify polymer morphology. Plasticizers can weaken intermolecular forces along the polymer chains, thus increasing free volume and lowering the glass transition temperature. For this reason, polymers with plasticizers have improved ductility.
  • Do plasticizers reduce intermolecular forces?
  • In general, plasticizers reduce intermolecular forces along the polymer chains, thus increasing free volume and chain movements (Immergut and Mark, 1965). The addition of plasticizer lowers the melt viscosity and elastic modulus of the polymers and decreases the glass transition temperature (Tg) (Han and Gennadios, 2005).