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It was found that TBAC is a relatively stable PVC plasticizer compared to traditional non-covalent plasticizers but is also surface active, and oxygen plasma treatment could be applied to TBAC plasticized PVC products to enhance surface hydrophilicity for improving the biocompatibility and antibacterial properties of PVC products. Tributyl acetyl citrate (TBAC), a widely-used "green

The molecular interfacial structure and plasticizer migration behavior of “green” plasticized poly (vinyl chloride) Xiaoxian Zhang,a Yaoxin Li,a Jeanne M. Hankett a and Zhan Chen *a Author affiliations Abstract Tributyl acetyl citrate (TBAC), a widely-used “green” plasticizer, has been extensively applied in products for daily use.

In this paper, a variety of analytical tools including sum frequency generation vibrational spectroscopy (SFG), coherent anti-Stokes Raman spectroscopy (CARS), contact angle goniometry (CA), and Fourier transform infrared spectroscopy (FTIR) were applied together to investigate the molecular structures of TBAC plasticized poly (vinyl chloride)

While it is known that the properties of polymer nanocomposites are largely dominated by the interfacial layer around nanoparticles, the molecular parameters controlling the interfacial layer structure and dynamics remain unknown. In this work we combine small-angle X-ray scattering, differential scanning calorimetry, and broadband dielectric spectroscopy to analyze the dependence of the

The molecular interfacial structure and plasticizer migration behavior of “green” plasticized poly (vinyl chloride). Physical Chemistry Chemical Physics 2015, 17 (6) , 4472-4482. https://doi.org/10.1039/C4CP05287K Xiaoxian Zhang, John N. Myers, Qinghuang Lin, Jeffery D. Bielefeld, Zhan Chen.