Progresses in Synthesis of Polycarboxylate Superplasticizer
It was shown in Fourier transform infrared spectroscopy (FITR) that the molecular structure of modified polycarboxylate superplasticizer (MPCE) contained sulfonic acid groups, carboxylic acid groups, polyethylene oxide vinyl groups, and other groups and had comb-shaped molecular structure.
Research progress on polycarboxylate based superplasticizers
Polycarboxylate ether/ester (PCE) superplasticizers are widely used due to their molecular structural designability, low dosage and high efficiency. However, their high sensitivity and strong interactions with clays in concrete reduce their dispersion and water-reduction capability, which can affect the performance of concrete seriously.
Structure-property relationships for polycarboxylate ether
Findings. 3 exhibited higher absolute negative ζ-potential values than COO while PCE copolymers with shorter side chains developed higher absolute negative ζ-potential values. On the other hand, the adsorption study demonstrated that decreasing the side chain lengths lead to higher adsorption of PCE copolymers while Copolymers with COO groups were found to be adsorbed more than
ODWH6XSHUSODVWLFL]HU - Institute of Physics
A highly adaptable polycarboxylate superplasticizer (PCE-2) was synthesized by free radical copolymerization in aqueous solution with isoprenol polyoxyethylene ether as macromonomer, acrylic acid and hydroxyethyl acrylate and 2-methacryloyloxyethyl phosphate as unsaturated monomers, mercaptopropionic acid as chain transfer agent, hydrogen
ODWHVXSHUODVWLFL]HU - Institute of Physics
showed that when acid/ether mole ratio was 4.0/1, P dosage was 8% of TPEG, rotating speed was 800rpm and reaction temperature was 60℃, synthetic polycarboxylate superplasticizer had the best comprehensive performance. 1.Introduction The polycarboxylate superplasticizer is mainly a liquid product on the market currently[1].The factory
- What is a polycarboxylate ether superplasticizer?
- The polycarboxylate ether superplasticizer is an additive commonly used in concrete engineering and has a wide range of applications. The PCE based admixture can significantly reduce the amount of cement and improve the fluidity and pumpability of concrete while ensuring the strength and durability of concrete.
- What is polycarboxylate superplasticizer (PCE)?
- Polycarboxylate superplasticizer (PCE), also known as polycarboxylate ether superplasticizer, is a new generation of high-performance concrete admixture.
- Can polycarboxylate based superplasticizer improve the crack resistance of concrete?
- The polycarboxylate based superplasticizer can improve the crack resistance of concrete. After adding an appropriate amount of water reducing agent in concrete, the internal structure of the concrete can be improved and the contraction and cracking of concrete can be reduced.
- What are the advantages of polycarboxylate based superplasticizer?
- Low dosage and high water reduction rate. The water reduction rate of polycarboxylate based superplasticizer can be as high as 45%, which can be used to prepare high-strength and high-performance concrete. Small loss when slump is light.
- How can Polycarboxylate ether reduce water and gray ratio?
- Reduce concrete water and gray ratio. Polycarboxylate ether superplasticizer can form a decentralized adsorption film in the concrete, reducing the contact between water and cement particles, thereby reducing the concrete water and gray ratio. By reducing the water and gray ratio, the strength and durability of the concrete can be improved.
- How to store PCE polycarboxylate superplasticizer?
- The PCE polycarboxylate superplasticizer should be stored in a cool, dry and well-ventilated place, avoiding direct sunlight and rain. At the same time, it should be kept away from fire and heat sources to prevent fire or explosion accidents. Water seepage problem.
