A novel quantitation method for phthalates in air using a
For the quantitation of phthalates present in air, conventional sampling and analytical techniques based on solvent extraction and gas chromatography (GC) system have generally been recommended , ; however, this conventional method suffers from a number of drawbacks relative to other phthalate quantitation methods in water or solids.
Rapid measurement of Phthalic acid Ester environmental
The analytical process of detecting PAEs using the ion mobility spectrometer is as follows: first, the sample solution with injected 5 μL was placed in the middle of the preceding of a sampling swipe, which made of PTFE could endure high temperature, and then inserted into the opening of the thermal desorption chamber after the solvent was
Airborne phthalates in indoor environment: Partition state
Based on previous research, the sampling and analysis methods for phthalate esters (PAEs) were improved by increasing the sampling flow of indoor air from 1 to 4 L/min, shortening the sampling duration from 8 to 2 hr. Meanwhile, through the optimization of chromatographic conditions, the concentrations of 9 additional PAE pollutants in indoor
Analytical Method Development and Chemometric Approach
In this study, an analytical method for the simultaneous determination of PAEs (dimethyl phthalate DMP, diethyl phthalate DEP, diisobutyl phthalate DiBP, dibutyl phthalate DBP, bis (2-ethylhexyl) phthalate DEHP, and di-n-octyl-phthalate DnOP) and BP-A was developed.
Determination of Selected Phthalates in Some Commercial
The developed method is a simple, sensitive, reliable and economical alternative for the determination of phthalates in the content of cosmetic products, it can be used to identify phthalate esters in different products after some modifications. Keywords: BBP; DBP; DEHP; DEP; DMP; HPLC-UV; Phthalates; cosmetics; method validation. Publication types
- Which phthalate is a validated measurement method?
- July 2017 This analytical method is a validated measurement procedure for the determination of several phthalates such as dimethyl phthalate, diethyl phthalate, diallyl phthalate, diisobutyl phthalate, dibutyl phthalate, benzyl butyl phthalate, dicyclohexyl phthalate, bis (2-ethylhexyl) phthalate and bis (2-propylheptyl) phthalate in workplace air.
- What is DMP phthalate & methanol?
- Dimethyl phthalate (DMP), diethyl phthalate (DEP) and dibutyl phthalate (DBP) were purchased from VWR. Methanol, 99.9 % HPLC grade, was purchased from Fisher Scientific. Millipore filter paper (pore size 0.45μm, Whatman filter paper) to purify all the solutions.
- Why is dimethyl phthalate less polar than DMP?
- DEP is less polar than dimethyl phthalate as it contains ethyl group where the number of carbons is increased and it elutes second in series. The retention time was 2.9 mins which is 0.5 mins longer than DMP. Table 2. Calibration plot for DEP; concentration vs. absorbance. Figure 3.
- How was phthalate derivatives analyzed?
- HPLC instrument was used for analysis of these phthalate derivatives. A reversed phase isocratic and gradient elution and UV detection method was used for the individual and simultaneous determination of these phthalate derivatives. HPLC was carried out using a C18 column and spectrophotometric detection at 230nm.
- How is phthalate quantified in gas chromatography-mass spectrometry (GC-MS)?
- The sample solution is analysed by means of gas chromatography-mass spectrometry (GC-MS). The quantitative determination is based on calibration functions obtained by means of multiple-point calibrations. The limit of quantification for an individual phthalate is between 0.015 and 0.096 mg/m 3.
- Which chromatography method is used to determine phthalates?
- The gas chromatography with electron capture detector (GC-ECD) was the most common method for the determination of phthalates in the environment , . The GC with flame ionization detector (GC-FID) was also used when phthalates were in polar solvents .
