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  • Which Green plasticizers are used for internal plasticization of PVC?
  • In this study, the tributhyl citrate (TBC), propargyl ether tributhyl citrate (PrTBC), oleic acid and poly (dimethylsiloxane) diglycidyl ether terminated (PDMS, Mn ≃ 800) have been used as four different green plasticizers to internal plasticization of PVC.
  • How are internal plasticized PVCs prepared?
  • In this study, the internally plasticized PVCs were prepared by four different green plasticizing agents. Self-plasticization of PVCs were performed by covalently bonding of TBC, PrTBC, oleic acid and PDMS (Mn ≃ 800) as internal plasticizers to PVC matrix.
  • How to self-plasticize PVC?
  • Self-plasticization of PVCs were performed by covalently bonding of TBC, PrTBC, oleic acid and PDMS (Mn ≃ 800) as internal plasticizers to PVC matrix. The prepared M-PVCs through different synthesis routes abbreviated with PVC-TBC 1, PVC-TBC 2, PVC-Oleic, and PVC-PDMS, respectively.
  • Is green plasticization useful for plasticization of PVC with higher Termal stability?
  • The results showed that this green approach is not only useful for plasticization of the PVC with higher termal stability, but also for inhibition of the migration of the plasticizer molecules.
  • What is the internal plasticizing mechanism of self-plasticizing PVC materials?
  • Internal plasticizing mechanism of self-plasticizing PVC materials. Kilpatrick and Clark (among others ) developed the lubricity theory for plasticization. In this theory, molecular lubrication is happening by the aid of plasticizer, which facilitate the movement of the chains over each other when a force applied to them .
  • Why are PVC oleic and PVC-TBC 2 prepared materials more flexible?
  • The prepared materials from PVC-HDI precursor (PVC-oleic and PVC-TBC 2) have a lower Tg compared to others. This can be related to the presence of the HDI at them, which caused the higher free volume at them and result in more flexibility. These materials due to their diverse Tg amounts can be employed in semi-rigid to flexible applications.